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            Abstract. The Global Ocean Data Analysis Project (GLODAP) is a synthesis effort providing regular compilations of surface to bottom ocean biogeochemical bottle data, with an emphasis on seawater inorganic carbon chemistry and related variables determined through chemical analysis of seawater samples. GLODAPv2.2023 is an update of the previous version, GLODAPv2.2022 (Lauvset et al., 2022). The major changes are as follows: data from 23 new cruises were added. In addition, a number of changes were made to the data included in GLODAPv2.2022. GLODAPv2.2023 includes measurements from more than 1.4 million water samples from the global oceans collected on 1108 cruises. The data for the now 13 GLODAP core variables (salinity, oxygen, nitrate, silicate, phosphate, dissolved inorganic carbon, total alkalinity, pH, chlorofluorocarbon-11 (CFC-11), CFC-12, CFC-113, CCl4, and SF6) have undergone extensive quality control with a focus on the systematic evaluation of bias. The data are available in two formats: (i) as submitted by the data originator but converted to World Ocean Circulation Experiment (WOCE) exchange format and (ii) as a merged data product with adjustments applied to minimize bias. For the present annual update, adjustments for the 23 new cruises were derived by comparing those data with the data from the 1085 quality-controlled cruises in the GLODAPv2.2022 data product using crossover analysis. SF6 data from all cruises were evaluated by comparison with CFC-12 data measured on the same cruises. For nutrients and ocean carbon dioxide (CO2), chemistry comparisons to estimates based on empirical algorithms provided additional context for adjustment decisions. The adjustments that we applied are intended to remove potential biases from errors related to measurement, calibration, and data-handling practices without removing known or likely time trends or variations in the variables evaluated. The compiled and adjusted data product is believed to be consistent to better than 0.005 in salinity, 1 % in oxygen, 2 % in nitrate, 2 % in silicate, 2 % in phosphate, 4 µmol kg−1 in dissolved inorganic carbon, 4 µmol kg−1 in total alkalinity, 0.01–0.02 in pH (depending on region), and 5 % in the halogenated transient tracers. The other variables included in the compilation, such as isotopic tracers and discrete CO2 fugacity (fCO2), were not subjected to bias comparison or adjustments. The original data, their documentation, and DOI codes are available at the Ocean Carbon and Acidification Data System of NOAA National Centers for Environmental Information (NCEI), which also provides access to the merged data product. This is provided as a single global file and as four regional ones – the Arctic, Atlantic, Indian, and Pacific oceans – under https://doi.org/10.25921/zyrq-ht66 (Lauvset et al., 2023). These bias-adjusted product files also include significant ancillary and approximated data, which were obtained by interpolation of, or calculation from, measured data. This living data update documents the GLODAPv2.2023 methods and provides a broad overview of the secondary quality control procedures and results.more » « less
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            The rapid melt of snow and sea ice during the Arctic summer provides a significant source of low-salinity meltwater to the surface ocean on the local scale. The accumulation of this meltwater on, under, and around sea ice floes can result in relatively thin meltwater layers in the upper ocean. Due to the small-scale nature of these upper-ocean features, typically on the order of 1 m thick or less, they are rarely detected by standard methods, but are nevertheless pervasive and critically important in Arctic summer. Observations during the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition in summer 2020 focused on the evolution of such layers and made significant advancements in understanding their role in the coupled Arctic system. Here we provide a review of thin meltwater layers in the Arctic, with emphasis on the new findings from MOSAiC. Both prior and recent observational datasets indicate an intermittent yet long-lasting (weeks to months) meltwater layer in the upper ocean on the order of 0.1 m to 1.0 m in thickness, with a large spatial range. The presence of meltwater layers impacts the physical system by reducing bottom ice melt and allowing new ice formation via false bottom growth. Collectively, the meltwater layer and false bottoms reduce atmosphere-ocean exchanges of momentum, energy, and material. The impacts on the coupled Arctic system are far-reaching, including acting as a barrier for nutrient and gas exchange and impacting ecosystem diversity and productivity.more » « less
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            Abstract. Systematic long-term studies on ecosystem dynamics are largely lacking from the East Antarctic Southern Ocean, although it is well recognized that they are indispensable to identify the ecological impacts and risks of environmental change. Here, we present a framework for establishing a long-term cross-disciplinary study on decadal timescales. We argue that the eastern Weddell Sea and the adjacent sea to the east, off Dronning Maud Land, is a particularly well suited area for such a study, since it is based on findings from previous expeditions to this region. Moreover, since climate and environmental change have so far been comparatively muted in this area, as in the eastern Antarctic in general, a systematic long-term study of its environmental and ecological state can provide a baseline of the current situation, which will be important for an assessment of future changes from their very onset, with consistent and comparable time series data underpinning and testing models and their projections. By establishing an Integrated East Antarctic Marine Research (IEAMaR) observatory, long-term changes in ocean dynamics, geochemistry, biodiversity, and ecosystem functions and services will be systematically explored and mapped through regular autonomous and ship-based synoptic surveys. An associated long-term ecological research (LTER) programme, including experimental and modelling work, will allow for studying climate-driven ecosystem changes and interactions with impacts arising from other anthropogenic activities. This integrative approach will provide a level of long-term data availability and ecosystem understanding that are imperative to determine, understand, and project the consequences of climate change and support a sound science-informed management of future conservation efforts in the Southern Ocean.more » « less
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            The international and interdisciplinary sea-ice drift expedition “The Multidisciplinary drifting Observatory for the Study of Arctic Climate” (MOSAiC) was conducted from October 2019 to September 2020. The aim of MOSAiC was to study the interconnected physical, chemical, and biological characteristics and processes from the atmosphere to the deep sea of the central Arctic system. The ecosystem team addressed current knowledge gaps and explored unknown biological properties over a complete seasonal cycle focusing on three major research areas: biodiversity, biogeochemical cycles, and linkages to the environment. In addition to the measurements of core properties along a complete seasonal cycle, dedicated projects covered specific processes and habitats, or organisms on higher taxonomic or temporal resolution in specific time windows. A wide range of sampling instruments and approaches, including sea-ice coring, lead sampling with pumps, rosette-based water sampling, plankton nets, remotely operated vehicles, and acoustic buoys, was applied to address the science objectives. Further, a broad range of process-related measurements to address, for example, productivity patterns, seasonal migrations, and diversity shifts, were made both in situ and onboard RV Polarstern. This article provides a detailed overview of the sampling approaches used to address the three main science objectives. It highlights the core sampling program and provides examples of habitat- or process-specific sampling. The initial results presented include high biological activities in wintertime and the discovery of biological hotspots in underexplored habitats. The unique interconnectivity of the coordinated sampling efforts also revealed insights into cross-disciplinary interactions like the impact of biota on Arctic cloud formation. This overview further presents both lessons learned from conducting such a demanding field campaign and an outlook on spin-off projects to be conducted over the next years.more » « less
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            Abstract. The Global Ocean Data Analysis Project (GLODAP) is asynthesis effort providing regular compilations of surface-to-bottom oceanbiogeochemical bottle data, with an emphasis on seawater inorganic carbonchemistry and related variables determined through chemical analysis ofseawater samples. GLODAPv2.2022 is an update of the previous version,GLODAPv2.2021 (Lauvset et al., 2021). The major changes are as follows: datafrom 96 new cruises were added, data coverage was extended until 2021, andfor the first time we performed secondary quality control on all sulfurhexafluoride (SF6) data. In addition, a number of changes were made todata included in GLODAPv2.2021. These changes affect specifically theSF6 data, which are now subjected to secondary quality control, andcarbon data measured on board the RV Knorr in the Indian Ocean in 1994–1995 whichare now adjusted using certified reference material (CRM) measurements made at the time. GLODAPv2.2022includes measurements from almost 1.4 million water samples from the globaloceans collected on 1085 cruises. The data for the now 13 GLODAP corevariables (salinity, oxygen, nitrate, silicate, phosphate, dissolvedinorganic carbon, total alkalinity, pH, chlorofluorocarbon-11 (CFC-11), CFC-12, CFC-113, CCl4,and SF6) have undergone extensive quality control with a focus onsystematic evaluation of bias. The data are available in two formats: (i) assubmitted by the data originator but converted to World Ocean CirculationExperiment (WOCE) exchange format and (ii) as a merged data product withadjustments applied to minimize bias. For the present annual update,adjustments for the 96 new cruises were derived by comparing those data withthe data from the 989 quality-controlled cruises in the GLODAPv2.2021 dataproduct using crossover analysis. SF6 data from all cruises wereevaluated by comparison with CFC-12 data measured on the same cruises. Fornutrients and ocean carbon dioxide (CO2) chemistry comparisons toestimates based on empirical algorithms provided additional context foradjustment decisions. The adjustments that we applied are intended to removepotential biases from errors related to measurement, calibration, and datahandling practices without removing known or likely time trends orvariations in the variables evaluated. The compiled and adjusted dataproduct is believed to be consistent to better than 0.005 in salinity, 1 % in oxygen, 2 % in nitrate, 2 % in silicate, 2 % in phosphate,4 µmol kg−1 in dissolved inorganic carbon, 4 µmol kg−1in total alkalinity, 0.01–0.02 in pH (depending on region), and 5 % inthe halogenated transient tracers. The other variables included in thecompilation, such as isotopic tracers and discrete CO2 fugacity(fCO2), were not subjected to bias comparison or adjustments. The original data, their documentation, and DOI codes are available at theOcean Carbon and Acidification Data System of NOAA NCEI (https://www.ncei.noaa.gov/access/ocean-carbon-acidification-data-system/oceans/GLODAPv2_2022/, last access: 15 August 2022). This site also provides access to themerged data product, which is provided as a single global file and as fourregional ones – the Arctic, Atlantic, Indian, and Pacific oceans –under https://doi.org/10.25921/1f4w-0t92 (Lauvset et al.,2022). These bias-adjusted product files also include significant ancillaryand approximated data, which were obtained by interpolation of, orcalculation from, measured data. This living data update documents theGLODAPv2.2022 methods and provides a broad overview of the secondary qualitycontrol procedures and results.more » « less
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            Effective data management plays a key role in oceanographic research as cruise-based data, collected from different laboratories and expeditions, are commonly compiled to investigate regional to global oceanographic processes. Here we describe new and updated best practice data standards for discrete chemical oceanographic observations, specifically those dealing with column header abbreviations, quality control flags, missing value indicators, and standardized calculation of certain properties. These data standards have been developed with the goals of improving the current practices of the scientific community and promoting their international usage. These guidelines are intended to standardize data files for data sharing and submission into permanent archives. They will facilitate future quality control and synthesis efforts and lead to better data interpretation. In turn, this will promote research in ocean biogeochemistry, such as studies of carbon cycling and ocean acidification, on regional to global scales. These best practice standards are not mandatory. Agencies, institutes, universities, or research vessels can continue using different data standards if it is important for them to maintain historical consistency. However, it is hoped that they will be adopted as widely as possible to facilitate consistency and to achieve the goals stated above.more » « less
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            null (Ed.)Abstract. The Global Ocean Data Analysis Project (GLODAP) is asynthesis effort providing regular compilations of surface-to-bottom oceanbiogeochemical data, with an emphasis on seawater inorganic carbon chemistryand related variables determined through chemical analysis of seawatersamples. GLODAPv2.2020 is an update of the previous version, GLODAPv2.2019.The major changes are data from 106 new cruises added, extension of timecoverage to 2019, and the inclusion of available (also for historicalcruises) discrete fugacity of CO2 (fCO2) values in the mergedproduct files. GLODAPv2.2020 now includes measurements from more than 1.2 million water samples from the global oceans collected on 946 cruises. Thedata for the 12 GLODAP core variables (salinity, oxygen, nitrate, silicate,phosphate, dissolved inorganic carbon, total alkalinity, pH, CFC-11, CFC-12,CFC-113, and CCl4) have undergone extensive quality control with afocus on systematic evaluation of bias. The data are available in twoformats: (i) as submitted by the data originator but updated to WOCEexchange format and (ii) as a merged data product with adjustments appliedto minimize bias. These adjustments were derived by comparing the data fromthe 106 new cruises with the data from the 840 quality-controlled cruises ofthe GLODAPv2.2019 data product using crossover analysis. Comparisons toempirical algorithm estimates provided additional context for adjustmentdecisions; this is new to this version. The adjustments are intended toremove potential biases from errors related to measurement, calibration, anddata-handling practices without removing known or likely time trends orvariations in the variables evaluated. The compiled and adjusted dataproduct is believed to be consistent to better than 0.005 in salinity, 1 % in oxygen, 2 % in nitrate, 2 % in silicate, 2 % in phosphate,4 µmol kg−1 in dissolved inorganic carbon, 4 µmol kg−1in total alkalinity, 0.01–0.02 in pH (depending on region), and 5 % inthe halogenated transient tracers. The other variables included in thecompilation, such as isotopic tracers and discrete fCO2, were notsubjected to bias comparison or adjustments. The original data and their documentation and DOI codes are available at theOcean Carbon Data System of NOAA NCEI(https://www.nodc.noaa.gov/ocads/oceans/GLODAPv2_2020/, lastaccess: 20 June 2020). This site also provides access to the merged dataproduct, which is provided as a single global file and as four regional ones– the Arctic, Atlantic, Indian, and Pacific oceans –under https://doi.org/10.25921/2c8h-sa89 (Olsen et al., 2020). Thesebias-adjusted product files also include significant ancillary andapproximated data. These were obtained by interpolation of, or calculationfrom, measured data. This living data update documents the GLODAPv2.2020methods and provides a broad overview of the secondary quality controlprocedures and results.more » « less
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            Abstract. The Global Ocean Data Analysis Project (GLODAP) is asynthesis effort providing regular compilations of surface to bottom oceanbiogeochemical data, with an emphasis on seawater inorganic carbon chemistryand related variables determined through chemical analysis of water samples.This update of GLODAPv2, v2.2019, adds data from 116 cruises to the previousversion, extending its coverage in time from 2013 to 2017, while also addingsome data from prior years. GLODAPv2.2019 includes measurements from morethan 1.1 million water samples from the global oceans collected on 840cruises. The data for the 12 GLODAP core variables (salinity, oxygen,nitrate, silicate, phosphate, dissolved inorganic carbon, total alkalinity,pH, CFC-11, CFC-12, CFC-113, and CCl4) have undergone extensive qualitycontrol, especially systematic evaluation of bias. The data are available intwo formats: (i) as submitted by the data originator but updated to WOCEexchange format and (ii) as a merged data product with adjustments appliedto minimize bias. These adjustments were derived by comparing the data fromthe 116 new cruises with the data from the 724 quality-controlled cruises ofthe GLODAPv2 data product. They correct for errors related to measurement,calibration, and data handling practices, taking into account any known orlikely time trends or variations. The compiled and adjusted data product isbelieved to be consistent to better than 0.005 in salinity, 1 % in oxygen,2 % in nitrate, 2 % in silicate, 2 % in phosphate, 4 µmol kg−1 in dissolved inorganic carbon, 4 µmol kg−1 in totalalkalinity, 0.01–0.02 in pH, and 5 % in the halogenated transienttracers. The compilation also includes data for several other variables,such as isotopic tracers. These were not subjected to bias comparison oradjustments. The original data, their documentation and DOI codes are available in theOcean Carbon Data System of NOAA NCEI(https://www.nodc.noaa.gov/ocads/oceans/GLODAPv2_2019/, last access: 17 September 2019). Thissite also provides access to the merged data product, which is provided as asingle global file and as four regional ones – the Arctic, Atlantic, Indian,and Pacific oceans – under https://doi.org/10.25921/xnme-wr20(Olsen et al., 2019). Theproduct files also include significant ancillary and approximated data.These were obtained by interpolation of, or calculation from, measured data.This paper documents the GLODAPv2.2019 methods and provides a broad overviewof the secondary quality control procedures and results.more » « less
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